Is H3+ cooling ever important in primordial gas?

Studies of the formation of metal-free Population III stars usually focus primarily on the role played by H2 cooling, on account of its large chemical abundance relative to other possible molecular or ionic coolants. However, while H2 is generally the most important coolant at low gas densities, it is not an effective coolant at high gas densities, owing to the low critical density at which it reaches local thermodynamic equilibrium (LTE) and to the large opacities that develop in its emission lines. It is therefore possible that emission from other chemical species may play an important role in cooling high density primordial gas. A particularly interesting candidate is the H3+ molecular ion. This ion has an LTE cooling rate that is roughly a billion times larger than that of H2, and unlike other primordial molecular ions such as H2+ or HeH+, it is not easily removed from the gas by collisions with H or H2. It is already known to be an important coolant in at least one astrophysical context -- the upper atmospheres of gas giants -- but its role in the cooling of primordial gas has received little previous study. In this paper, we investigate the potential importance of H3+ cooling in primordial gas using a newly-developed H3+ cooling function and the most detailed model of primordial chemistry published to date. We show that although H3+ is, in most circumstances, the third most important coolant in dense primordial gas (after H2 and HD), it is nevertheless unimportant, as it contributes no more than a few percent of the total cooling. We also show that in gas irradiated by a sufficiently strong flux of cosmic rays or X-rays, H3+ can become the dominant coolant in the gas, although the size of the flux required renders this scenario unlikely to occur.Comment: 60 pages, 22 figures. Submitted to MNRA

Statistics of conductance and shot-noise power for chaotic cavities

We report on an analytical study of the statistics of conductance, $g$, and shot-noise power, $p$, for a chaotic cavity with arbitrary numbers $N_{1,2}$ of channels in two leads and symmetry parameter $\beta = 1,2,4$. With the theory of Selberg's integral the first four cumulants of $g$ and first two cumulants of $p$ are calculated explicitly. We give analytical expressions for the conductance and shot-noise distributions and determine their exact asymptotics near the edges up to linear order in distances from the edges. For $0<g<1$ a power law for the conductance distribution is exact. All results are also consistent with numerical simulations.Comment: 7 pages, 3 figures. Proc. of the 3rd Workshop on Quantum Chaos and Localisation Phenomena, Warsaw, Poland, May 25-27, 200

Chemical Abundances and the Metagalactic Radiation Field at High Redshift

We have carried out model calculations of the photoionized intergalactic medium (IGM) to determine the effects on the predicted ionic column densities due to uncertainties in the published dielectronic recombination (DR) rate coefficients. Based on our previous experimental work and a comparison of published theoretical DR rates, we estimate there is in general a factor of 2 uncertainty in existing DR rates used for modeling the IGM. We demonstrate that this uncertainty results in factors of ~1.9 uncertainty in the predicted N V and Si IV column densities, ~1.6 for O VI, and ~1.7 for C IV. We show that these systematic uncertainties translate into a systematic uncertainty of up to a factor of ~3.1 in the Si/C abundance ratio inferred from observations. The inferred IGM abundance ratio could thus be less than the solar Si/C ratio or greater than 3 times the solar ratio. If the latter is true, then it suggests the metagalactic radiation field is not due purely to active galactic nuclei, but includes a significant stellar component. Lastly, column density ratios of Si IV to C IV versus C II to C IV are often used to constrain the decrement in the metagalactic radiation field at the He II absorption edge. We show that the variation in the predicted Si IV to C IV ratio due to a factor of 2 uncertainty in the DR rates is almost as large as that due to a factor of 10 change in the decrement. Laboratory measurements of the relevant DR resonance strengths and energies are the only unambiguous method to remove the effects of these atomic physics uncertainties from models of the IGM

Properties of short-range and long-range correlation energy density functionals from electron-electron coalescence

The combination of density functional theory with other approaches to the many-electron problem through the separation of the electron-electron interaction into a short-range and a long-range contribution is a promising method, which is raising more and more interest in recent years. In this work some properties of the corresponding correlation energy functionals are derived by studying the electron-electron coalescence condition for a modified (long-range-only) interaction. A general relation for the on-top (zero electron-electron distance) pair density is derived, and its usefulness is discussed with some examples. For the special case of the uniform electron gas, a simple parameterization of the on-top pair density for a long-range only interaction is presented and supported by calculations within the ``extended Overhauser model''. The results of this work can be used to build self-interaction corrected short-range correlation energy functionals.Comment: revised version, to appear in Phys. Rev.

Dielectronic recombination data for astrophysical applications: Plasma rate-coefficients for Fe^q+ (q=7-10, 13-22) and Ni^25+ ions from storage-ring experiments

This review summarizes the present status of an ongoing experimental effort to provide reliable rate coefficients for dielectronic recombination of highly charged iron ions for the modeling of astrophysical and other plasmas. The experimental work has been carried out over more than a decade at the heavy-ion storage-ring TSR of the Max-Planck-Institute for Nuclear Physics in Heidelberg, Germany. The experimental and data reduction procedures are outlined. The role of previously disregarded processes such as fine-structure core excitations and trielectronic recombination is highlighted. Plasma rate coefficients for dielectronic recombination of Fe^q+ ions (q=7-10, 13-22) and Ni^25+ are presented graphically and in a simple parameterized form allowing for easy use in plasma modeling codes. It is concluded that storage-ring experiments are presently the only source for reliable low-temperature dielectronic recombination rate-coefficients of complex ions.Comment: submitted for publication in the International Review of Atomic and Molecular Physics, 8 figures, 3 tables, 68 reference

Simple model of the static exchange-correlation kernel of a uniform electron gas with long-range electron-electron interaction

A simple approximate expression in real and reciprocal spaces is given for the static exchange-correlation kernel of a uniform electron gas interacting with the long-range part only of the Coulomb interaction. This expression interpolates between the exact asymptotic behaviors of this kernel at small and large wave vectors which in turn requires, among other thing, information from the momentum distribution of the uniform electron gas with the same interaction that have been calculated in the G0W0 approximation. This exchange-correlation kernel as well as its complement analogue associated to the short-range part of the Coulomb interaction are more local than the Coulombic exchange-correlation kernel and constitute potential ingredients in approximations for recent adiabatic connection fluctuation-dissipation and/or density functional theory approaches of the electronic correlation problem based on a separate treatment of long-range and short-range interaction effects.Comment: 14 pages, 14 figures, to be published in Phys. Rev.

Van der Waals forces in density functional theory: perturbational long-range electron interaction corrections

Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron interaction in the Hamiltonian into short- and long-range components. We propose a "range-separated hybrid" functional based on a local density approximation for the short-range exchange-correlation energy, combined with a long-range exact exchange energy. Long-range correlation effects are added by a second-order perturbational treatment. The resulting scheme is general and is particularly well-adapted to describe van der Waals complexes, like rare gas dimers.Comment: 8 pages, 1 figure, submitted to Phys. Rev.

Long-range/short-range separation of the electron-electron interaction in density functional theory

By splitting the Coulomb interaction into long-range and short-range components, we decompose the energy of a quantum electronic system into long-range and short-range contributions. We show that the long-range part of the energy can be efficiently calculated by traditional wave function methods, while the short-range part can be handled by a density functional. The analysis of this functional with respect to the range of the associated interaction reveals that, in the limit of a very short-range interaction, the short-range exchange-correlation energy can be expressed as a simple local functional of the on-top pair density and its first derivatives. This provides an explanation for the accuracy of the local density approximation (LDA) for the short-range functional. Moreover, this analysis leads also to new simple approximations for the short-range exchange and correlation energies improving the LDA.Comment: 18 pages, 14 figures, to be published in Phys. Rev.

Astrophysical Relevance of Storage-Ring Electron-Ion Recombination Experiments

The relevance of storage-ring electron-ion recombination experiments for astrophysics is outlined. In particular, the role of low-energy dielectronic-recombination resonances is discussed. A bibliographic compilation of electron-ion recombination measurements with cosmically abundant ions is provided.Comment: 8 pages, 3 figures, 1 table, 77 references, Proceedings of the 14th International Conference on the Physics of Highly Charged Ions, Cofu, Tokyo, Septmber 1-5, 2008, to be published in J. Phys. Conf. Se